Dual Fano and Lorentzian line profile poperties of autoionizing states

TL;DR

This study demonstrates that autoionizing states can naturally exhibit both Fano and Lorentzian line profiles depending on the process, offering new avenues for quantum phase control and challenging classical recombination models.

Contribution

The paper reveals that autoionizing states can inherently display both Fano and Lorentzian profiles without external laser influence, expanding understanding of quantum interference effects.

Findings

Autoionizing states can have both Fano and Lorentzian profiles naturally.

Different excitation pathways lead to different line profiles for the same state.

Results challenge the classical two-step model of dielectronic recombination.

Abstract

Ott et al. (Science (340, 716 (2013)) successfully transferred Fano profile into Lorentzian lineshape using an intense infrared laser, after excitation of autoionizing states in helium by attosecond XUV pulse. This is a very important step forward of quantum phase control. However, here we show experimentally that an autoionizing state can have both Fano and Lorentzian behavior naturally, depending on the process involved. This study utilized the inverse process of photon absorption ionization, i.e. electron ion recombination with photon emission, making sure the resonant autoionizing state is not perturbed by the laser fields. Our result implies that excitation of the state through different paths can lead to different Fano profiles for the same resonant state. This allows more options for the combination of laser fields and lead to more opportunities for quantum phase control. Our result also indicates the breakdown of the classical two step picture for dielectronic recombination.