Spectroscopic study of some diatomic molecules via the proper quantization rule

TL;DR

This paper applies the proper quantization rule to solve the Schrödinger equation for diatomic molecules, providing a simple and accurate method to determine energy levels across various models and molecules.

Contribution

It introduces a versatile method based on proper quantization for calculating energy states in diatomic molecules using solvable potential models.

Findings

Accurately computed energy levels for H₂ and CO molecules.

Determined electronic state spectra for NO and ICl.

Validated the method's effectiveness against previous techniques.

Abstract

Spectroscopic techniques are very essential tools in studying electronic structures, spectroscopic constants and energetic properties of diatomic molecules. These techniques are also required for parametrization of new method based on theoretical analysis and computational calculations. In this research, we apply the proper quantization rule in spectroscopic study of some diatomic molecules by solving the Schr\"odinger equation with two solvable quantum molecular systems-Tietz-Wei and shifted Deng-Fan potential models for their approximate nonrelativistic energy states via an appropriate approximation to the centrifugal term. We show that the energy levels can be determined from its ground state energy. The beauty and simplicity of the method applied in this study is that, it can be applied to any exactly as well as approximately solvable models. The validity and accuracy of the method is tested with previous techniques via numerical computation for H$_2$ and CO diatomic molecules. The result also include energy spectrum of 5 different electronic states of NO and 2 different electronic state of ICl.