A single crystal Co2+ fluoride pyrochlore antiferromagnet

TL;DR

This study reports the synthesis and magnetic characterization of a new cobalt-based pyrochlore, NaSrCo$_2$F$_7$, which exhibits strong magnetic frustration and no spin freezing down to 3 K, making it a promising model for frustrated magnetism.

Contribution

It introduces a new cobalt-based pyrochlore with detailed structural and magnetic properties, highlighting its potential as a frustrated antiferromagnet with weak bond disorder.

Findings

Exhibits strong antiferromagnetic interactions with ${ heta}_{CW}$ = -127 K

Shows no spin freezing until 3 K despite strong frustration

Possesses large magnetic moments and geometric frustration

Abstract

We report the crystal growth, crystal structure and basic magnetic properties of a new cobalt-based pyrochlore, NaSrCo$_2$F$_7$. Na and Sr are completely disordered on the non-magnetic large atom A sites, while magnetic S=3/2 Co$^{2+}$ fully occupies the pyrochlore lattice B sites. This system exhibits an isotropic magnetic susceptibility with strong antiferromagnetic interactions (${\theta}_{CW}$ = -127(1)), a large effective moment (${\rho_{eff}}$ = 5.9(1) ${\mu_B}$/Co) and no spin freezing until 3 K. Thus NaSrCo$_2$F$_7$ is a geometrically frustrated antiferromagnet with a frustration index f = -${\theta_{CW}}$/T$_f$ = 42. AC susceptibility, DC susceptibility, and heat capacity are utilized to characterize the spin freezing at low temperatures. We propose that NaSrCo$_2$F$_7$, compared here to the related material NaCaCo$_2$F$_7$, may be the realization of a frustrated pyrochlore antiferromagnet with weak bond disorder. The strong magnetic frustration at an easily accessible temperature and the availability of large single crystals make this one of the potentially interesting alternatives to the more commonly studied rare earth oxide pyrochlores.