M\"ossbauer and Magnetic Studies of Surfactant Mediated Ca-Mg Doped Ferrihydrite Nanoparticles

TL;DR

This study synthesizes ultrafine Ca-Mg co-doped ferrihydrite nanoparticles and investigates their phase evolution and magnetic properties, revealing size-dependent superparamagnetism and phase transformations through Mössbauer and magnetic analyses.

Contribution

It presents a novel surfactant-mediated co-precipitation method for synthesizing Ca-Mg co-doped ferrihydrite nanoparticles and characterizes their phase evolution and magnetic behavior.

Findings

Ultrafine amorphous ferrihydrite particles were synthesized with 2-5 nm size.

Superparamagnetism was observed in 8 nm hematite nanoparticles.

Crystallite size increased with annealing temperature, affecting magnetic properties.

Abstract

Ultrafine (2-5 nm) particles of amorphous Ca-Mg co-doped ferrihydrite have been synthesized by surfactant mediated co-precipitation method. The evolution of the amorphous ferrihydrite by Ca-Mg co-doping is quite different from our earlier investigations on individual Ca and Mg doping studies. Amorphous phase of ferrihydrite for the present study has been confirmed by X-ray diffraction (XRD) and M\"ossbauer spectroscopy at room temperature and low temperatures (40 K and 20 K). Hematite nanoparticles with crystallite size about 8, 38 and 70 nm were obtained after annealing the as-prepared samples at 400, 600 and 800$^0$C respectively in air atmosphere. Superparamagnetism has been found in 8 nm sized hematite nanoparticles which has been confirmed from the magnetic hysteresis loop with zero remanent magnetization and coercive field and also from the superparamagnetic doublet of its room temperature M\"ossbauer spectrum. The magnetic properties of the 38 and 70 nm sized particles have been studied by room temperature magnetic hysteresis loop measurements and M\"ossbauer spectroscopy. The coercive field in these hematite nanoparticles increases with increasing particle size. Small amount of spinel MgFe$_{2}$O$_{4}$ phase has been detected in the 800$^0$C annealed sample.