Lithium Ion Solvation and Diffusion in Bulk Organic Electrolytes from First Principles and Classical Reactive Molecular Dynamics

TL;DR

This study uses first principles and classical reactive molecular dynamics to analyze how lithium ions are solvated and diffuse in different organic electrolytes, revealing how solvent structure affects ionic mobility and battery performance.

Contribution

The paper provides detailed insights into Li ion solvation structures and diffusion behavior in EC, EMC, and their mixture, using advanced simulation techniques to inform electrolyte design.

Findings

Li ions are solvated by carbonyl or ether oxygen atoms and sometimes PF6-

Li+ prefers tetrahedral coordination regardless of solvent

Diffusivity is higher in EMC than EC, correlating with solvation strength

Abstract

Lithium-ion battery performance is strongly influenced by the ionic conductivity of the electrolyte, which depends on the speed at which Li ions migrate across the cell and relates to their solvation structure. The choice of solvent can greatly impact both solvation and diffusivity of Li ions. We use first principles molecular dynamics to examine the solvation and diffusion of Li ions in the bulk organic solvents ethylene carbonate (EC), ethyl methyl carbonate (EMC), and a mixture of EC/EMC. We find that Li ions are solvated by either carbonyl or ether oxygen atoms of the solvents and sometimes by the PF$_6^-$ anion. Li$^+$ prefers a tetrahedrally-coordinated first solvation shell regardless of which species are involved, with the specific preferred solvation structure dependent on the organic solvent. In addition, we calculate Li diffusion coefficients in each electrolyte, finding slightly larger diffusivities in the linear carbonate EMC compared to the cyclic carbonate EC. The magnitude of the diffusion coefficient correlates with the strength of Li$^+$ solvation. Corresponding analysis for the PF$_6^-$ anion shows greater diffusivity associated with a weakly-bound, poorly defined first solvation shell. These results may be used to aid in the design of new electrolytes to improve Li-ion battery performance.