Analyses of microstructural and elastic properties of porous SOFC cathodes based on focused ion beam tomography

TL;DR

This study reconstructs 3D microstructures of porous SOFC cathodes using FIB/SEM tomography to analyze their microstructural and elastic properties, highlighting the impact of image processing parameters on measurement accuracy.

Contribution

It provides a detailed analysis of how image segmentation thresholds affect microstructural and elastic property estimations in SOFC cathodes using FIB/SEM tomography.

Findings

Porosity and tortuosity are highly sensitive to segmentation thresholds.

Elastic modulus correlates strongly with porosity.

Microstructural parameters influence elastic property simulations.

Abstract

Mechanical properties of porous SOFC electrodes are largely determined by their microstructures. Measurements of the elastic properties and microstructural parameters can be achieved by modelling of the digitally reconstructed 3D volumes based on the real electrode microstructures. However, the reliability of such measurements is greatly dependent on the processing of raw images acquired for reconstruction. In this work, the actual microstructures of La0.6Sr0.4Co0.2Fe0.8O3-d (LSCF) cathodes sintered at an elevated temperature were reconstructed based on dual-beam FIB/SEM tomography. Key microstructural and elastic parameters were estimated and correlated. Analyses of their sensitivity to the grayscale threshold value applied in the image segmentation were performed. The important microstructural parameters included porosity, tortuosity, specific surface area, particle and pore size distributions, and inter-particle neck size distribution, which may have varying extent of effect on the elastic properties simulated from the microstructures using FEM. Results showed that different threshold value range would result in different degree of sensitivity for a specific parameter. The estimated porosity and tortuosity were more sensitive than surface area to volume ratio. Pore and neck size were found to be less sensitive than particle size. Results also showed that the modulus was essentially sensitive to the porosity which was largely controlled by the threshold value.