Unconventional phase selection in high-driven systems: A complex metastable structure prevails over simple stable phases

TL;DR

This study reveals that in high-driven systems like glassy alloys, complex metastable structures can form and grow rapidly, challenging traditional notions of phase stability and selection during devitrification.

Contribution

The paper uncovers a new devitrification pathway involving complex metastable phases, with detailed structural analysis and insights into nucleation and growth mechanisms.

Findings

A large cubic metastable phase precipitates with a 1.4 nm lattice parameter.

The structure of the cubic phase containing ~140 atoms is solved.

Rapid growth is facilitated by high tolerance to point defects.

Abstract

Phase selection in deeply undercooled liquids and devitrified glasses during heating involves complex interplay between the barriers to nucleation and the ability for these nuclei to grow. During the devitrification of glassy alloys, complicated metastable structures often precipitate instead of simpler, more stable compounds. Here, we access this unconventional type of phase selections by investigating an Al-10%Sm system, where a complicated cubic structure first precipitates with a large lattice parameter of 1.4 nm. We not only solve the structure of this "big cubic" phase containing ~140 atoms but establish an explicit interconnection between the structural orderings of the amorphous alloy and the cubic phase, which provides a low-barrier nucleation pathway at low temperatures. The surprising rapid growth of the crystal is attributed to its high tolerance to point defects, which minimize the short-scale atomic rearrangements to form the crystal. Our study suggests a new scenario of devitrification, where phase transformation proceeds initially without partitioning through a complex intermediate crystal phase.