Single crystal study of layered U$_{n}$RhIn$_{3n+2}$ materials: case of the novel U$_{2}$RhIn$_{8}$ compound

TL;DR

This study investigates the novel U$_{2}$RhIn$_{8}$ compound's structural, magnetic, and electronic properties, revealing antiferromagnetic order at 117 K, pressure-dependent T$_{N}$, and itinerant 5f electron behavior, expanding understanding of layered uranium intermetallics.

Contribution

The paper reports the synthesis, structural characterization, and magnetic properties of U$_{2}$RhIn$_{8}$, a new layered uranium compound, and compares it with related systems, providing insights into its electronic and magnetic behavior.

Findings

U$_{2}$RhIn$_{8}$ orders antiferromagnetically below 117 K.

T$_{N}$ increases under hydrostatic pressure up to 3.2 GPa.

Uranium 5f electrons exhibit itinerant character in this compound.

Abstract

We report on the single crystal properties of the novel U$_{2}$RhIn$_{8}$ compound studied in the context of parent URhIn$_{5}$ and UIn$_{3}$ systems. The compounds were prepared by In self-flux method. U$_{2}$RhIn$_{8}$ adopts the Ho$_{2}$CoGa$_{8}$-type structure with lattice parameters a $= 4.6056(6)$ \AA\ and c $= 11.9911(15)$ \AA. The behavior of U$_{2}$RhIn$_{8}$ strongly resembles that of the related URhIn$_{5}$ and UIn$_{3}$ with respect to magnetization, specific heat and resistivity except for magnetocrystalline anisotropy developing with lowering dimensionality in the series UIn$_{3}$ vs. U$_{2}$RhIn$_{8}$ and URhIn$_{5}$. U$_{2}$RhIn$_{8}$ orders antiferromagnetically below T$_{\textrm{N}}$ $= 117$ K and exhibits a slightly enhanced Sommerfeld coefficient $\gamma = 47$ mJ$\cdot$mol$^{-1}\cdot$K$^{-2}$. Magnetic field leaves the value of N\'{e}el temperature for both URhIn$_{5}$ and U$_{2}$RhIn$_{8}$ unaffected up to 9 T. On the other hand, T$_{\textrm{N}}$ is increasing with applying hydrostatic pressure up to 3.2 GPa. The weak temperature dependence of $\chi(T)$ in all studied compounds might be attributed to the mainly itinerant nature of 5f electrons. The character of uranium 5f electron states of U$_{2}$RhIn$_{8}$ was studied by first principles calculations based on the density functional theory. The overall phase diagram of U$_{2}$RhIn$_{8}$ is discussed in the context of magnetism in the related URhX$_{5}$ and UX$_{3}$ (X = In, Ga) compounds.