Enhanced weak ferromagnetism and conductivity in hole-doped pyrochlore iridate Y2Ir2O7

TL;DR

This study investigates the magnetic and electronic properties of Y2Ir2O7 and its hole-doped variants, revealing enhanced ferromagnetism and conductivity due to Ir oxidation state changes, with implications for topological states.

Contribution

It provides a systematic analysis of magnetic and electronic behavior in hole-doped pyrochlore iridates, highlighting the role of Ir oxidation states in magnetic phenomena.

Findings

Hole doping enhances ferromagnetism and conductivity.

Ir5+ presence correlates with increased ferromagnetism.

Weak ferromagnetism coexists with antiferromagnetic background.

Abstract

Pyrochlore iridates have recently attracted growing interest in condensed matter physics because of their potential for realizing new topological states. In order to achieve such quantum states, it is essential to understand themagnetic properties of these compounds, as their electronic structures are strongly coupled with theirmagnetic ground states. In this work, we report a systematic study of the magnetic properties of pyrochlore Y2Ir2O7 and its hole-doped compounds by performing magnetic, electron spin resonance, electrical transport, and x-ray photoelectron spectroscopy (XPS) measurements. We demonstrate the existence of weak ferromagnetism on top of a large antiferromagnetic background in the undoped compound. Hole doping by calcium was found to enhance both the ferromagnetism and the electrical conductivity. The XPS characterization shows the coexistence of Ir4+ and Ir5+ in the undoped compound, and the amount of Ir5+ increases with Ca doping, which highlights the possible origins of the weak ferromagnetism associated with the formation of Ir5+.We also observe a vertical shift in the M-H curves after field cooling, which may arise from a strong coupling between the ferromagnetic phase and the antiferromagnetic background.