Liquid structure and temperature invariance of sound velocity in supercooled Bi melt

TL;DR

This study investigates the invariance of sound velocity in supercooled liquid bismuth, revealing a continuous structural evolution and challenging previous hypotheses about its behavior near melting.

Contribution

It provides high-precision measurements of sound velocity and neutron diffraction data showing continuous structural changes in supercooled liquid Bi.

Findings

Sound velocity remains invariant over a 60°C temperature range.

Neutron diffraction indicates continuous short-range order modification.

Liquid Bi's structure evolves similarly to other pnictide liquids.

Abstract

Structural rearrangement of liquid Bi in the vicinity of the melting point has been proposed due to the unique temperature invariant sound velocity observed above the melting temperature, the low symmetry of Bi in the solid phase and the necessity of overheating to achieve supercooling. The existence of this structural rearrangement is examined by measurements on supercooled Bi. The sound velocity of liquid Bi was measured into the supercooled region to high accuracy and it was found to be invariant over a temperature range of ca. 60 degrees, from 35 degrees above the melting point to ca. 25 degrees into the supercooled region. The structural origin of this phenomenon was explored by neutron diffraction structural measurements in the supercooled temperature range. These measurements indicate a continuous modification of the short range order in the melt. The structure of the liquid is analyzed within a quasi-crystalline model and is found to evolve continuously, similar to other known liquid pnictide systems. The results are discussed in the context of two competing hypotheses proposed to explain properties of liquid Bi near the melting: (i) liquid bismuth undergoes a structural rearrangement slightly above melting (ii) liquid Bi exhibits a broad maximum in the sound velocity located incidentally at the melting temperature.