Exciton diffusion, end quenching, and exciton-exciton annihilation in individual air-suspended carbon nanotubes

TL;DR

This study investigates how exciton diffusion influences luminescence in individual air-suspended carbon nanotubes, revealing length and power dependence, and providing quantitative parameters like diffusion length and quantum yield.

Contribution

It introduces a combined experimental and modeling approach to quantify exciton diffusion, end quenching, and exciton-exciton annihilation in carbon nanotubes, with new insights into their interplay.

Findings

Determined exciton diffusion lengths for various chiralities.

Observed diameter-dependent photoluminescence quantum yields.

Revealed the one-dimensional coalescence process through simulations.

Abstract

Luminescence properties of carbon nanotubes are strongly affected by exciton diffusion, which plays an important role in various nonradiative decay processes. Here we perform photoluminescence microscopy on hundreds of individual air-suspended carbon nanotubes to elucidate the interplay between exciton diffusion, end quenching, and exciton-exciton annihilation processes. A model derived from random-walk theory as well as Monte Carlo simulations are utilized to analyze nanotube length dependence and excitation power dependence of emission intensity. We have obtained the values of exciton diffusion length and absorption cross section for different chiralities, and diameter-dependent photoluminescence quantum yield have been observed. The simulations have also revealed the nature of a one-dimensional coalescence process, and an analytical expression for the power dependence of emission intensity is given.