Near-equilibrium universality and bounds on efficiency in quasi-static regime with finite source and sink

TL;DR

This paper derives universal bounds on efficiency at maximum work in quasi-static thermodynamics with finite sources and sinks, revealing near-equilibrium efficiency expressions and their dependence on system sizes.

Contribution

It introduces universal efficiency formulas and bounds for quasi-static processes with finite reservoirs, extending finite-time thermodynamics results to classical thermodynamics.

Findings

Efficiency at maximum work is given by a universal formula in near-equilibrium.

Efficiency bounds depend on the relative size of source and sink.

Efficiency beyond linear response is briefly discussed.

Abstract

We show the validity of some results of finite-time thermodynamics, also within the quasi-static framework of classical thermodynamics. First, we consider the efficiency at maximum work (EMW) from finite source and sink modelled as identical thermodynamic systems. The near-equilibrium regime is characterized by expanding the internal energy upto second order (i.e. upto linear response) in the difference of initial entropies of the source and the sink. It is shown that the efficiency is given by a universal expression $2 \eta_C / (4-\eta_C)$, where $\eta_C$ is the Carnot efficiency. Then, different sizes of source and sink are treated, by combining different numbers of copies of the same thermodynamic system. The efficiency of this process is found to be ${\boldsymbol\eta}_0 = \eta_C/ (2-\gamma \eta_C)$, where the parameter $\gamma$ depends only on the relative size of the source and the sink. This implies that within the linear response theory, EMW is bounded as ${\eta_C}/{2} \le {{\boldsymbol\eta}}_0 \le {\eta_C}/{(2 - \eta_C)}$, where the upper (lower) bound is obtained with a sink much larger (smaller) in size than the source. We also remark on the behavior of the efficiency beyond linear response.