The chemistry and spatial distribution of small hydrocarbons in UV-irradiated molecular clouds: the Orion Bar PDR

TL;DR

This study investigates the distribution and chemistry of small hydrocarbons in the Orion Bar PDR, revealing that gas-phase reactions, rather than PAH photodestruction, primarily produce these molecules in high UV-flux environments.

Contribution

It provides new observational data and models on hydrocarbon chemistry in PDRs, including detection of new lines and isotopologue fractionation, challenging previous assumptions about PAH destruction.

Findings

Hydrocarbon lines constitute ~40% of the survey.

Gas-phase reactions explain hydrocarbon abundances without PAH destruction.

The [C2H]/[c-C3H2] ratio decreases with UV attenuation.

Abstract

We study the spatial distribution and chemistry of small hydrocarbons in the Orion Bar PDR. We used the IRAM-30m telescope to carry out a millimetre line survey towards the Orion Bar edge, complemented with ~2'x2' maps of the C2H and c-C3H2 emission. We analyse the excitation of the detected hydrocarbons and constrain the physical conditions of the emitting regions with non-LTE radiative transfer models. We compare the inferred column densities with updated gas-phase photochemical models including 13CCH and C13CH isotopomer fractionation. ~40% of the lines in the survey arise from hydrocarbons (C2H, C4H, c-C3H2, c-C3H, C13CH, 13CCH, l-C3H and l-H2C3). We detect new lines from l-C3H+ and improve its rotational spectroscopic constants. Anions or deuterated hydrocarbons are not detected: [C2D]/[C2H]<0.2%, [C2H-]/[C2H]<0.007% and [C4H-]/[C4H]<0.05%. Our gas-phase models can reasonably match the observed column densities of most hydrocarbons (within factors <3). Since the observed spatial distribution of the C2H and c-C3H2 emission is similar but does not follow the PAH emission, we conclude that, in high UV-flux PDRs, photodestruction of PAHs is not a necessary requirement to explain the observed abundances of the smallest hydrocarbons. Instead, gas-phase endothermic reactions (or with barriers) between C+, radicals and H2 enhance the formation of simple hydrocarbons. Observations and models suggest that the [C2H]/[c-C3H2] ratio (~32 at the PDR edge) decreases with the UV field attenuation. The observed low cyclic-to-linear C3H column density ratio (<3) is consistent with a high electron abundance (Xe) PDR environment. In fact, the poorly constrained Xe gradient influences much of the hydrocarbon chemistry in the more UV-shielded gas. We propose that reactions of C2H isotopologues with 13C+ and H atoms can explain the observed [C13CH]/[13CCH]=1.4(0.1) fractionation level.