Magnetism of Hexagonal Mn1.5X0.5Sn (X = Cr, Mn, Fe, Co) Nanomaterials
R. Fuglsby, P. Kharel, W. Zhang, S. Valloppilly, Y. Huh, D. J., Sellmyer

TL;DR
This study investigates the magnetic properties of hexagonal Mn1.5X0.5Sn nanomaterials with X = Cr, Mn, Fe, Co, prepared via arc-melting and melt spinning, revealing their magnetic behavior, anisotropy, and effects of annealing.
Contribution
It provides new insights into the magnetic characteristics and enhancement methods of Mn1.5X0.5Sn nanomaterials with different transition metal substitutions.
Findings
Highest saturation magnetization of 458 emu/cm3 for Mn1.5Fe0.5Sn.
Curie temperatures below 300 K, improved to 273 K after annealing.
Most samples exhibit spin-glass-like behavior at low temperatures.
Abstract
Mn1.5X0.5Sn (X = Cr, Mn, Fe, Co) nanomaterials in the hexagonal Ni2In-type crystal structure have been prepared using arc-melting and melt spinning. All the rapidly quenched Mn1.5X0.5Sn alloys show moderate saturation magnetizations with the highest value of 458 emu/cm3 for Mn1.5Fe0.5Sn, but their Curie temperatures are less than 300 K. All samples except the Cr containing one show spin-glass-like behavior at low temperature. The magnetic anisotropy constants calculated from the high-field magnetization curves at 100 K are on the order of 1 Merg/cm3. The vacuum annealing of the ribbons at 550 oC significantly improved their magnetic properties with the Curie temperature increasing from 206 K to 273 K for Mn1.5Fe0.5Sn.
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