Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

TL;DR

This study investigates the magnetic structure and spin reorientation in CeMnAsO, revealing high-temperature antiferromagnetic order, low-temperature spin reorientation, and Ce-Mn coupling, contributing to understanding magnetic interactions in oxypnictides.

Contribution

It provides detailed neutron diffraction and magnetization data on CeMnAsO, highlighting the spin reorientation mechanism and Ce-Mn coupling in a 1111-type oxypnictide for the first time.

Findings

CeMnAsO exhibits high-temperature C-type antiferromagnetic order with Mn moments along c-axis.

Below 35 K, Mn moments reorient to the ab-plane, and Ce moments order antiferromagnetically in the ab-plane.

The magnetic structure involves a local-moment antiferromagnetic insulator with dominant J1 interaction.

Abstract

Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the "1111"-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn$^{2+}$ ($S=5/2$) moments pointing along the \textit{c}-axis below a relatively high N\'{e}el temperature of $T_{\rm N} = 345$ K. Below $T_{\rm SR} = 35$ K, two instantaneous transitions occur where the Mn moments reorient from the $c$-axis to the \textit{ab}-plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the \textit{ab}-plane. Another transition to a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) $\mu_{B}$ and 0.81(4)$\mu_{B}$, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction ($J_{1}$) is dominant with $J_{2}<J_{1}/2$ in the context of $J_{1}-J_{2}-J_{c}$ model. The spin reorientation transition driven by the coupling between rare earth Ce and transition metal seems to be common to Mn, Fe and Cr ions, but not to Co and Ni ions in the iso-structural oxypnictides. A schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is proposed.