Structural and Magnetic Phase Transitions in MnTe-MnSe solid solutions

TL;DR

This study investigates how doping MnSe with Te affects its structural and magnetic phase transitions, revealing a suppression of the NiAs phase and evidence of magnetostructural coupling through neutron diffraction analysis.

Contribution

It provides new insights into the phase behavior and magnetostructural coupling in MnTe-MnSe solid solutions with varying Te content.

Findings

NiAs phase diminishes with Te doping

Structural transition temperature decreases with Te content

Magnetostructural coupling observed in thermal evolution

Abstract

Neutron diffraction studies as a function of temperature on solid solutions of MnSe and MnTe in the Se rich region are presented. Interestingly as Te is doped in MnSe, the structural transformation to NiAs phase diminishes, both in terms of \% fraction of compound as well as in terms of transition temperature. In MnTe$_{0.3}$Se$_{0.7}$, the NaCl to NiAs phase transformation occurs at about 40K and although it is present at room temperature in MnTe$_{0.5}$Se$_{0.5}$, its volume fraction is only about 10\% of the total volume of sample. The magnetic ordering temperature of the cubic phase decreases with increasing Te content while the hexagonal phase orders at the same temperature as in MnSe. Anomalies in thermal evolution of lattice parameters at magnetic ordering as well as structural transition temperatures indicate presence of magnetostructural coupling in these compounds.