About the First Layer Effect in Surface Enhanced Spectroscopy
V.P. Chelibanov, A.M. Polubotko
TL;DR
This paper clarifies that surface-enhanced spectroscopy's enhancement mechanism is purely electrodynamical, with no chemical contribution, challenging previous assumptions about chemical effects.
Contribution
It provides evidence that the enhancement in surface-enhanced spectroscopy is solely electrodynamical, refuting the chemical enhancement hypothesis.
Findings
No chemical enhancement observed in surface-enhanced spectroscopy
Enhancement is purely electrodynamical in nature
Challenges previous chemical enhancement assumptions
Abstract
It is demonstrated that there is no chemical enhancement in Surface Enhanced spectroscopy, but the enhancement is of a pure electrodynamical nature.
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Taxonomy
TopicsSpectroscopy and Quantum Chemical Studies · Electrochemical Analysis and Applications · Electrostatics and Colloid Interactions