Tungsten Nanowire Based Hyperbolic Metamaterial Emitters for Near-field Thermophotovoltaic Applications

TL;DR

This paper theoretically demonstrates that tungsten nanowire hyperbolic metamaterial emitters significantly enhance near-field thermophotovoltaic energy conversion efficiency and power output by leveraging epsilon-near-zero and hyperbolic modes.

Contribution

It introduces a novel tungsten nanowire HMM emitter design and analyzes its impact on TPV performance, showing substantial efficiency improvements over plain tungsten emitters.

Findings

Power output increased by 1.85 times with nanowire HMM at 10 nm gap

Conversion efficiency improved from 19.5% to 31.5% with a thin TPV cell

Maximum efficiency of 32.2% achieved with 3 um thick cell

Abstract

Recently, near-field radiative heat transfer enhancement across nanometer vacuum gaps has been intensively studied between two hyperbolic metamaterials (HMMs) due to unlimited wavevectors and high photonic density of state. In this work, we theoretically analyze the energy conversion performance of a thermophotovoltaic (TPV) cell made of In0.2Ga0.8Sb when paired with a HMM emitter composed of tungsten nanowire arrays embedded in Al2O3 host at nanometer vacuum gaps. Fluctuational electrodynamics integrated with effective medium theory and anisotropic thin-film optics is used to calculate the near-field radiative heat transfer. It is found that the spectral radiative energy is enhanced by the epsilon-near-zero and hyperbolic modes at different polarizations. As a result, the power output from a semi-infinite TPV cell is improved by 1.85 times with the nanowire HMM emitter over that with a plain tungsten emitter at a vacuum gap of 10 nm. Moreover, by using a thin TPV cell with 10 um thickness, the conversion efficiency can be greatly improved from 19.5% to 31.5% without affecting the power generation, due to the total internal reflection occurring at the bottom cell interface that minimizes the sub-bandgap spectral radiative energy. Furthermore, the effects of a TPV cell and a nanowire emitter with finite thicknesses are also studied. The result shows that the maximum efficiency of 32.2% is achieved with an optimal cell thickness of 3 um while the nanowire HMM emitter should be thick enough to be opaque. The fundamental understanding and insights obtained here will facilitate the design and application of novel materials in enhancing near-field TPV energy conversion.