Observation of the Sb2S3-type post-post-GdFeO3-perovskite: A model structure for high density ABX3 and A2X3 phases

TL;DR

This paper reports the discovery of a new high-pressure Sb2S3-type post-post-perovskite structure in GdFeO3-type fluoroperovskite, providing insights into phase transitions relevant for Earth's deep mantle and exoplanet modeling.

Contribution

It presents the first experimental observation of a Sb2S3-type post-post-perovskite phase in GdFeO3, expanding understanding of high-pressure phase transitions in ABX3 systems.

Findings

Identification of Sb2S3-type post-post-perovskite structure at high pressure

Crystallographic orientation data from single-crystal techniques

Insights into transition mechanisms and structural relationships

Abstract

Ten years have passed since the description of the perovskite to post-perovskite transition in MgSiO3 and its' impact on the mineralogy and rheology of the D" region at the base of the Earth's mantle. Much work has explored the mechanisms operating during this transformation and their influence on seismic response. In parallel, calculations in ABX3 systems have identified potential structures for a denser post-post-perovskite phase occurring at higher pressures. However, experiments have yet to elucidate any higher pressure form, beyond the CaIrO3-type. Here we describe the structures and transformations that lead to the crystallisation of a post-post-perovskite of Sb2S3-type in a GdFeO3-type fluoroperovskite at high pressure conditions. The use of single-crystal techniques gives unique access to the relative crystallographic orientations of all polymorphs. We use this information to extend this description to include other calculated and observed forms that are competitive in ABX3 and A2X3 stoichiometries (e.g. Sb2S3, a-Gd2S3, Be3N2) and provide substantial information on inter-relationships between these structures, which is critical to the interpretation of transition mechanisms, predicting transition sequences, to the expression of directional properties in those transformed structures when assessing their suitability to modelling e.g. their rheological response in deep-Earth and exoplanet interiors.