Comparison of grain texture in round Bi2212 and flat Bi2223 superconducting wires and its relation to high critical current densities

TL;DR

This paper compares the grain textures of Bi2212 round wires and Bi2223 tapes, revealing how their microstructures influence critical current densities and isotropic superconducting behavior, with implications for magnet applications.

Contribution

It demonstrates that Bi2212's unique biaxial texture and azimuthal c-axis rotation enable high Jc and isotropic properties, unlike Bi2223.

Findings

Bi2212 exhibits a dominant a-axis growth texture with azimuthal c-axis rotation.

Bi2223 shows only uniaxial c-axis texture without in-plane texture.

Bi2223 displays Jc hysteresis indicative of weak links, absent in Bi2212.

Abstract

Why Bi2Sr2CaCu2Ox (Bi2212) allows high critical current density Jc in round wires rather than only in the anisotropic tape form demanded by all other high temperature superconductors is important for future magnet applications. Here we compare the local texture of state-of-the-art Bi2212 and Bi2223 ((Bi,Pb)2Sr2Ca2Cu3O10), finding that round wire Bi2212 generates a dominant a-axis growth texture that also enforces a local biaxial texture (FWHM <15{\deg}) while simultaneously allowing the c-axes of its polycrystals to rotate azimuthally along and about the filament axis so as to generate macroscopically isotropic behavior. By contrast Bi2223 shows only a uniaxial (FWHM <15{\deg}) c-axis texture perpendicular to the tape plane without any in-plane texture. Consistent with these observations, a marked, field-increasing, field-decreasing Jc(H) hysteresis characteristic of weak-linked systems appears in Bi2223 but is absent in Bi2212 round wire. Growth-induced texture on cooling from the melt step of the Bi2212 Jc optimization process appears to be the key step in generating this highly desirable microstructure.