Electronic and magnetic properties of Ti4O7 predicted by self-interaction corrected density functional theory

TL;DR

This study uses self-interaction corrected density functional theory to explore the electronic and magnetic properties of Ti4O7, revealing a new antiferromagnetic ground state and analyzing how electronic structures depend on stoichiometry and strain.

Contribution

It predicts a novel antiferromagnetic ground state for Ti4O7 and demonstrates the robustness of this state under various strain conditions using ASIC methods.

Findings

Predicted a new antiferromagnetic ground state in Ti4O7.

Electronic properties depend on oxygen deficiency and strain.

ASIC with α=0.5 effectively describes Ti-O phases.

Abstract

Understanding electronic properties of sub-stoichiometric phases of titanium oxide such as Magn\'eli phase Ti4O7 is crucial in designing and modeling resistive switching devices. Here we present our study on Magn\'eli phase Ti4O7 together with rutile TiO2 and Ti2O3 using density functional theory methods with atomic-orbital-based self-interaction correction (ASIC). We predict a new antiferromagnetic ground state in the low temperature phase (or LT phase), and we explain energy difference with a competing antiferromagnetic state using a Heisenberg model. The predicted energy ordering of these states in the LT phase is calculated to be robust in a wide range of modeled isotropic strain. We have also investigated the dependence of the electronic structures of the Ti-O phases on stoichiometry. The splitting of titanium t2g orbitals is enhanced with increasing oxygen deficiency as Ti-O is reduced. The electronic properties of all these phases can be reasonably well described by applying ASIC with a standard value for transition metal oxides of the empirical parameter {\alpha} of 0.5 representing the magnitude of the applied self-interaction correction.