An orientationally ordered helical fluid phase in a quasi-one-dimensional system of confined hard spheres

TL;DR

This study demonstrates a continuous phase transition in a confined hard sphere system from an isotropic fluid to an orientationally ordered helical fluid, revealing long-range orientational order despite short-range interactions.

Contribution

It introduces the discovery of a helical fluid phase with long-range orientational order in a quasi-one-dimensional system, supported by simulations and analytical theory.

Findings

Transition from isotropic to helical fluid at high density

Presence of topological defects affecting chirality

Long-range orientational order despite short-range interactions

Abstract

We use a series of molecular dynamics simulations, and analytical theory, to demonstrate that a system of hard spheres confined to a narrow cylindrical channel exhibits a continuous phase transition from an isotropic fluid at low densities, to an orientationally ordered, but translationally disordered, helical fluid at high densities. The ordered fluid phase contains small sections of helix separated by topological defects that change the direction of the twist, altering the local chirailty. The defects break up the translational order, but the fluid develops long range orientational order. An analysis of the particle packings show that the length separation between defects controls the geometrical properties of the helical sections, including the orientation, and that pairs of defects experience a weak, but long range attraction resulting from entropic free volumes effects. These collective long range interactions overcome the restrictions on quasi-one-dimensional transitions, even though the particle-particle interaction is short ranged.