Non-additive simple potentials for pre-programmed self-assembly

TL;DR

This paper introduces a simple, accessible model for self-assembling complex 2D structures using a binary mixture of particles with isotropic interactions, enabling targeted nanostructure fabrication.

Contribution

The study presents a novel, easy-to-implement model that achieves diverse 2D self-assembled structures through minimal geometrical and interaction parameters.

Findings

Successfully self-assembled multiple complex structures

Model is compatible with current experimental techniques

Potential for practical nano-fabrication applications

Abstract

A major goal in nanoscience and nanotechnology is the self-assembly of any desired complex structure with a system of particles interacting through simple potentials. To achieve this objective, intense experimental and theoretical efforts are currently concentrated in the development of the so called "patchy" particles. Here we follow a completely different approach and introduce a very accessible model to produce a large variety of pre-programmed two-dimensional (2D) complex structures. Our model consists of a binary mixture of particles that interact through isotropic in plane interactions that is able to self-assemble into targeted lattices by the appropriate choice of a small number of geometrical parameters and interaction strengths. We study the system using Monte Carlo computer simulations and, despite its simplicity, we are able to self assemble potentially useful structures such as chains, stripes, Kagome, twisted Kagome, honeycomb, square, Archimedean and quasicrystaline tilings. Our model is designed such that it may be imediately implemented in experiments using existing techniques to build particles with different shapes and interactions. Thus, it represents a promising strategy for bottom-up nano-fabrication.