Anisotropic magnetodielectric coupling behavior of Ca3Co1.4Rh0.6O6 due to geometrically frustrated magnetism

TL;DR

This study reveals anisotropic magnetodielectric coupling in Ca3Co1.4Rh0.6O6, driven by geometrically frustrated magnetism, with robust glassy magnetic behavior and a unique one-third saturation step in magnetization and dielectric responses.

Contribution

It demonstrates anisotropic magnetodielectric coupling in a geometrically frustrated spin-chain system, highlighting a correlation between magnetic and dielectric properties not previously observed.

Findings

Glassy-like magnetic behavior with strong frequency dependence

Robustness of magnetic and dielectric responses to external magnetic fields

Presence of a one-third saturation step in magnetization and dielectric measurements

Abstract

We have investigated the magnetic, dielectric and magnetodielectric (MDE) behavior of a geometrically frustrated spin-chain system, Ca3Co1.4Rh0.6O6, in the single crystalline form for different orientations. The results bring out that the magnetic behavior of this compound is by itself interesting in the sense that this compound exhibits an anisotropic glassy-like magnetic behavior with a huge frequency dependence of ac susceptibility peak for an orientation along the spin-chain in the range 30-60 K; this behavior is robust to applications of large external magnetic fields (H) unlike in canonical spin-glasses. The temperature dependence of dielectric constant also shows strong frequency dependence with similar robustness to H. The isothermal H-dependent dielectric results at low temperatures establishes anisotropic MDE coupling. It is intriguing to note that there is a 'step' roughly at one-third of saturation values as in the case of isothermal magnetization curves for same temperatures (for orientation along spin-chain), a correlation hitherto unrealized for geometrically frustrated systems.