Tunable Band gap of Iron-Doped Lanthanum-Modified Bismuth Titanate Synthesized by the Thermal Decomposition of a Secondary Phase

TL;DR

This study presents a new high-temperature calcination method to synthesize pure iron-doped lanthanum-modified bismuth titanate with a tunable and reduced band gap, avoiding secondary phases for improved optoelectronic applications.

Contribution

A novel synthesis route using high-temperature calcination to produce pure Fe-doped BLT with a tunable band gap by decomposing secondary phases.

Findings

Pure Fe-BLT phase achieved at high calcination temperatures.

Band gap reduction observed due to thermal decomposition of BiFeO3.

Method applicable to other complex oxides for optoelectronic devices.

Abstract

The photoelectric properties of complex oxides have prompted interest in materials with a tunable band gap, because the absorption The substitution of iron atoms in La-modified bismuth titanate (BLT) can lead to dramatic improvements in the band gap, however, the substitution of iron atoms in BLT without forming a BiFeO3 secondary phase is quite challenging. Therefore, a series of Fe-doped BLT (Fe-BLT) samples were characterized using a solid reaction at various calcination temperatures (300~900{\deg}C) to remove the secondary phase. The structural and optical properties were analyzed by X-ray diffraction and ultraviolet-visible absorption spectroscopy. This paper reports a new route to synthesize a pure Fe-BLT phase with a reduced optical band gap by high temperature calcination due to the thermal decomposition of BiFeO3 during high temperature calcination. This simple route to reduce the second phase can be adapted to other complex oxides for use in emerging oxide optoelectronic devices.