Magnetic properties of geometrically frustrated SrGd2O4

TL;DR

This study investigates the magnetic behavior of SrGd2O4, revealing complex phase transitions and magnetic interactions, notably influenced by dipolar effects due to Gd3+ ions, differing from other SrLn2O4 compounds.

Contribution

First detailed magnetic phase diagram of SrGd2O4 highlighting the role of dipolar interactions and unique low-temperature magnetic properties.

Findings

Identified two zero-field phase transitions at 2.73 and 0.48 K.

Mapped magnetic phase diagram showing complex transitions with field orientation.

Gd3+ ions' zero orbital angular momentum reduces spin-orbit effects, emphasizing dipolar interactions.

Abstract

A study of the magnetic properties of the frustrated rare earth oxide SrGd2O4 has been completed using bulk property measurements of magnetization, susceptibility and specific heat on single crystal samples. Two zero-field phase transitions have been identified at 2.73 and 0.48 K. For the field, H, applied along the a and b axes, a single boundary is identified that delineates the transition from a low field, low temperature magnetically ordered regime to a high field, high temperature paramagnetic phase. Several field-induced transitions, however, have been observed with H || c. The measurements have been used to map out the magnetic phase diagram of SrGd2O4, suggesting that it is a complex system with several competing magnetic interactions. The low-temperature magnetic behavior of SrGd2O4 is very different compared to the other SrLn2O4 (Ln = Lanthanide) compounds, even though all of the SrLn2O4 compounds are isostructural, with the magnetic ions forming a low-dimensional lattice of zigzag chains that run along the c axis. The differences are likely to be due to the fact that in the ground state Gd3+ has zero orbital angular momentum and therefore the spin-orbit interactions, which are crucial for other SrLn2O4 compounds, can largely be neglected. Instead, given the relatively short Gd3+-Gd3+ distances in SrGd2O4, dipolar interactions must be taken into account for this antiferromagnet alongside the Heisenberg exchange terms.