Slow ground state molecules from matrix isolation sublimation

TL;DR

This paper presents a method to generate cold $^7$Li$_2$ molecules using sublimation from a neon matrix, enabling studies of low-temperature molecular physics with potential applications in quantum science.

Contribution

The authors demonstrate a novel cryogenic molecular beam source from matrix sublimation, with detailed characterization and insights into molecule formation mechanisms.

Findings

Achieved translational temperatures of 6-8 K in the molecular beam.

Measured molecular densities around 10^9 cm^-3.

Observed potential molecule formation from atom mating in the matrix.

Abstract

We describe the generation and properties of a cryogenic beam of $^7$Li$_2$ dimers from sublimation of a neon matrix where lithium atoms have been implanted via laser ablation of solid precursors of metallic lithium or lithium hydride (LiH). Different sublimation regimes lead to pulsed molecular beams with different temperatures, densities and forward velocities. With laser absorption spectroscopy these parameters were measured using the molecular $^7$Li$_2$ (R) transitions A$^1\Sigma_u^+(v'=4,J'=J''+1)\leftarrow $X$^1\Sigma_g^+ (v''=0,J''=0,1,3)$. In a typical regime, sublimating a matrix at 16 K, translational temperatures of 6--8 K with a drift velocity of 130 m$\,$s$^{-1}$ in a free expanding pulsed beam with molecular density of 10$^9$ cm$^{-3}$, averaged along the laser axis, were observed. Rotational temperatures around 5--7 K were obtained. In recent experiments we were able to monitor the atomic Li signal -- in the D2 line -- concomitantly with the molecular signal in order to compare them as a function of the number of ablation pulses. Based on the data and a simple model, we discuss the possibility that a fraction of these molecules are being formed in the matrix, by mating atoms from different ablation pulses, which would open up the way to formation of other more interesting and difficult molecules to be studied at low temperatures. Such a source of cryogenic molecules have possible applications encompassing fundamental physics tests, quantum information studies, cold collisions, chemistry, and trapping.