Crossover from Room-temperature Double-channel Ballistic Transport to Single-channel Ballistic Transport in Zigzag Graphene Nanoribbons

TL;DR

This paper explains the experimental transition from double-channel to single-channel ballistic transport in zigzag graphene nanoribbons at room temperature by modeling edge spin-flip scattering induced by spin-orbit coupling.

Contribution

It introduces a model linking edge spin-flip scattering to conductance crossover in zigzag GNRs, aligning theory with recent experimental findings.

Findings

Conductance transitions from G0 to G0/2 with length increase.

Edge spin-flip scattering causes wave-function superposition.

Edge coupling removes the edge degree of freedom.

Abstract

Very recently, it was demonstrated explicitly that a zigzag graphene nanoribbon (GNR) exhibits a crossover of conductance from G0 to G0/2 with increasing the length (G0 = 2e2/h is the quantum of conductance) even at room-temperature [Baringhaus, et al. Nature 506, 349 (2014)]. Such a result is puzzling as none of previous theories seem to match the experimental observations. Here, we propose a model to explain the crossover from double-channel to single-channel ballistic transport in zigzag GNR. The sp3 distortion of carbon atoms at the GNR edges induces a large spin-orbit coupling on the edges atoms, which enhances spin-flip scattering of edge states of the zigzag GNR. With sufficient spin-flip scattering, the wave-function of edge states becomes a superposition of the spin-up and spin-down components. Then the coupling of the two edges becomes important. This removes the edge degree of freedom in the zigzag GNR and results in the evolution of the conductance from G0 to G0/2 with increasing the length.