Signatures of spin-glass behavior in the induced magnetic moment system PrRuSi3

TL;DR

This study reveals spin-glass behavior in PrRuSi3 linked to dynamic crystal field level fluctuations, despite evidence of long-range magnetic order from muSR, highlighting complex magnetic phenomena in this intermetallic compound.

Contribution

It demonstrates that spin-glass behavior in PrRuSi3 arises from dynamic fluctuations of crystal field levels, contrasting with traditional static magnetic order explanations.

Findings

Spin-glass signatures observed at 9.8 K in susceptibility and heat capacity.

Muon spin relaxation indicates long-range magnetic order with small moments.

Inelastic neutron scattering shows excitations near 2.4 and 14.7 meV.

Abstract

We have investigated the magnetic and transport properties of a ternary intermetallic compound PrRuSi3 using dc magnetization, ac susceptibility, specific heat, electrical resistivity, neutron diffraction, inelastic neutron scattering and muSR measurements. The magnetic susceptibility and specific heat data reveal the signatures of spin-glass behavior in PrRuSi3 with a freezing temperature of 9.8 K. At low magnetic fields, we observe two sharp anomalies (at 4.9 and 8.6 K) in magnetic susceptibility data. In contrast, the specific heat data show only a broad Schottky-type anomaly centered around 10 K. However, muSR reveals very low frequency coherent oscillations at 1.8 K with an onset of fast relaxation below 12 K indicating a long range magnetically ordered ground state with very small moment. On the other hand, no magnetic Bragg peaks are observed in low temperature neutron diffraction data at 1.8 K. These two contradictory ground states, spin-glass versus magnetic order, can be explained if the spin-glass behavior in PrRuSi3 is considered due to the dynamic fluctuations of the crystal field levels as has been proposed for spin-glass behavior in PrAu2Si2. Two sharp inelastic excitations near 2.4 meV and 14.7 meV are observed in the inelastic neutron scattering (INS) spectra between 4 K and 50 K. Further, exchange coupling J_ex obtained from the analysis of INS data with CEF model provides evidence for the spontaneously induced magnetic order with a CEF-split singlet (Gamma_t4) ground state. However, the exchange coupling seems to be close to the critical value for the induced moment magnetism, therefore we tend to believe that the dynamic fluctuations between the ground state singlet and excited doublet CEF levels is responsible for spin-glass behavior in PrRuSi3.