Investigations of the singlet ground state system: PrIrSi3

TL;DR

This study comprehensively investigates PrIrSi3, revealing a singlet ground state with complex magnetic behavior, crystal electric field effects, and possible magnetic ordering above 30 K, using multiple experimental techniques.

Contribution

First detailed analysis of PrIrSi3 showing a singlet ground state with magnetic correlations and muSR evidence of magnetic ordering above bulk transition temperatures.

Findings

Identified a magnetic phase transition at 12.2 K.

Detected crystal electric field excitations at 8.5 and 18.5 meV.

Observed magnetic ordering signatures above 30 K in muSR data.

Abstract

We report our comprehensive study of physical properties of a ternary intermetallic compound PrIrSi3 investigated by dc magnetic susceptibility chi(T), isothermal magnetization M(H), thermo-remnant magnetization M(t), ac magnetic susceptibility chi_ac(T), specific heat C_p(T), electrical resistivity rho(T), muon spin relaxation (muSR) and inelastic neutron scattering (INS) measurements. A magnetic phase transition is marked by a sharp anomaly at T_tr = 12.2 K in chi(T) measured at low applied fields which is also reflected in the C_p(T) data through a weak anomaly at 12 K. An irreversibility between the zero field cooled and field cooled chi(T) data below 12.2 K and a very large relaxation time of M(t) indicates the presence of ferromagnetic correlation. The magnetic part of specific heat shows a broad Schottky-type anomaly near 40~K due to the crystal electric field (CEF) effect. An extremely small value of magnetic entropy below 12 K suggests a CEF-split singlet ground state which is confirmed from our analysis of INS data. The INS spectra show two prominent inelastic excitations at 8.5 meV and 18.5 meV that could be well accounted by a CEF model. The CEF splitting energy between the ground state singlet and the first excited doublet is found to be 92 K. Our muSR data reveal a possible magnetic ordering below 30 K which is much higher than that found from the specific heat and magnetic susceptibility measurements. This could be due to the presence of short range correlations well above the long range magnetic ordering or due to the electronic changes induced by muons. The induced moment magnetism in the singlet ground state system PrIrSi3 with such a large splitting energy of 92 K is quite surprising.