Frequency ratio of two optical clock transitions in $^{171}$Yb$^+$ and constraints on the time-variation of fundamental constants
R. M. Godun, P. B. R. Nisbet-Jones, J. M. Jones, S. A. King, L. A. M., Johnson, H. S. Margolis, K. Szymaniec, S. N. Lea, K. Bongs, and P. Gill

TL;DR
This paper reports the first direct measurement of the frequency ratio of two optical clock transitions in singly-ionized ytterbium-171, achieving high precision and setting improved constraints on the possible variation of fundamental constants over time.
Contribution
It provides the first direct measurement of the frequency ratio of two Yb+ optical clock transitions without a cesium standard, with high accuracy, and refines constraints on fundamental constant variations.
Findings
First direct measurement of the frequency ratio in Yb+
Achieved absolute frequencies with $6\times 10^{-16}$ uncertainty
Improved constraints on the time-variation of fundamental constants
Abstract
Singly-ionized ytterbium, with ultra-narrow optical clock transitions at 467 nm and 436 nm, is a convenient system for the realization of optical atomic clocks and tests of present-day variation of fundamental constants. We present the first direct measurement of the frequency ratio of these two clock transitions, without reference to a cesium primary standard, and using the same single ion of 171Yb+. The absolute frequencies of both transitions are also presented, each with a relative standard uncertainty of . Combining our results with those from other experiments, we report a three-fold improvement in the constraint on the time-variation of the proton-to-electron mass ratio, year, along with an improved constraint on time-variation of the fine structure constant, …
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