Asymptotically exponential hitting times and metastability: a pathwise approach without reversibility
R. Fernandez, F. Manzo, F. R. Nardi, E. Scoppola

TL;DR
This paper develops a general, non-reversible pathwise approach to analyze metastability and hitting times in Markov processes, providing explicit bounds and conditions for exponential behavior without relying on reversibility or specific initial measures.
Contribution
It introduces a novel, general framework for metastability analysis that applies to non-reversible Markov processes and offers explicit bounds on hitting time distributions.
Findings
Provides explicit bounds on corrections to exponentiality.
Eliminates confusion among different metastability conditions.
Introduces early asymptotic exponential behavior for unbounded systems.
Abstract
We study the hitting times of Markov processes to target set , starting from a reference configuration or its basin of attraction. The configuration can correspond to the bottom of a (meta)stable well, while the target could be either a set of saddle (exit) points of the well, or a set of further (meta)stable configurations. Three types of results are reported: (1) A general theory is developed, based on the path-wise approach to metastability, which has three important attributes. First, it is general in that it does not assume reversibility of the process, does not focus only on hitting times to rare events and does not assume a particular starting measure. Second, it relies only on the natural hypothesis that the mean hitting time to is asymptotically longer than the mean recurrence time to or . Third, despite its mathematical simplicity, the approach…
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Taxonomy
TopicsMarkov Chains and Monte Carlo Methods · Stochastic processes and statistical mechanics · Advanced Thermodynamics and Statistical Mechanics
