Temperature-activated layer-breathing vibrations in few-layer graphene

TL;DR

This study reveals temperature-dependent activation of layer-breathing vibrations in few-layer graphene, showing that high temperatures enable detection of vibrations suppressed at room temperature due to surface adsorption.

Contribution

It demonstrates the temperature-activated nature of layer-breathing modes in graphene and models their thickness dependence using coupled oscillators.

Findings

LBM frequency decreases with increasing layer number

LBM Raman response appears only above 600 K

Surface adsorption suppresses LBM at lower temperatures

Abstract

We investigated the low-frequency Raman spectra of freestanding few-layer graphene (FLG) at varying temperatures (400 - 900 K) controlled by laser heating. At high temperature, we observed the fundamental Raman mode for the lowest-frequency branch of rigid-plane layer-breathing mode (LBM) vibration. The mode frequency redshifts dramatically from 81 cm-1 for bilayer to 23 cm-1 for 8-layer. The thickness dependence is well described by a simple model of coupled oscillators. Notably, the LBM Raman response is unobservable at room temperature, and it is turned on at higher temperature (>600 K) with a steep increase of Raman intensity. The observation suggests that the LBM vibration is strongly suppressed by molecules adsorbed on the graphene surface, but is activated as desorption occurs at high temperature.