Explaining Thermodynamic-Like Behaviour In Terms of Epsilon-Ergodicity
Roman Frigg, Charlotte Werndl

TL;DR
This paper proposes that gases exhibit thermodynamic-like behavior if they are epsilon-ergodic, meaning ergodic except for a small measure of phase space, providing a nuanced explanation beyond traditional ergodicity.
Contribution
It introduces the concept of epsilon-ergodicity as a refined condition explaining thermodynamic behavior, addressing limitations of classical ergodic assumptions.
Findings
Evidence suggests relevant systems are epsilon-ergodic.
Epsilon-ergodicity explains thermodynamic-like behavior.
Challenges traditional objections based on KAM and Markus-Meyer theorems.
Abstract
Why do gases reach equilibrium when left to themselves? The canonical answer, originally proffered by Boltzmann, is that the systems have to be ergodic. This answer is now widely regarded as flawed. We argue that some of the main objections, in particular, arguments based on the KAM-theorem and the Markus-Meyer theorem, are beside the point. We then argue that something close to Boltzmann's proposal is true: gases behave thermodynamic-like if they are epsilon-ergodic, i.e., ergodic on the phase space except for a small region of measure epsilon. This answer is promising because there is evidence that relevant systems are epsilon-ergodic.
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Taxonomy
TopicsAdvanced Thermodynamics and Statistical Mechanics · Phase Equilibria and Thermodynamics · Quantum chaos and dynamical systems
