Lattice effects on ferromagnetism in perovskite ruthenates

TL;DR

This study reveals that ferromagnetism in perovskite ruthenates is highly sensitive to lattice strain, demonstrating a parabolic relationship between Curie temperature and bond length, and achieving higher Tc through structural tuning.

Contribution

It clarifies the effect of A-site disorder on Tc and establishes a parabolic Tc versus bond length relationship, advancing understanding of structure-property correlations in ruthenates.

Findings

Tc exhibits a parabolic dependence on mean bond length <A-O>.

Maximum Tc of ~177 K occurs at a specific bond length where t=1.

Ferromagnetism is highly sensitive to lattice strain in ruthenates.

Abstract

Ferromagnetism and its evolution in the orthorhombic perovskite system Sr1-xCaxRuO3 have been widely believed to correlate with the structural distortion. The recent development of high-pressure synthesis of the Ba substituted Sr1-yBayRuO3 makes it possible to study ferromagnetism over a broader phase diagram, which includes new orthorhombic Imma and the cubic phases. However, the chemical substitutions introduce the A-site disorder effect on Tc, which complicates determination of the relationship between ferromagnetism and the structural distortion. By clarifying the site disorder effect on Tc in several new series of ruthenates in which the average bond length <A-O> keeps the same, but the bond-length variance varies, we are able to demonstrate a parabolic curve of Tc versus mean bond length <A-O>. A much higher Tc ~ 177 K than that found in orthorhombic SrRuO3 can be obtained from the curve at a bond length <A-O> which makes the geometric factor t = <A-O>/(sqrt(2)<Ru-O>) = 1. This new result reveals not only that the ferromagnetism in the ruthenates is extremely sensitive to the lattice strain, but also that it has an important implication for exploring the structure-property relationship in a broad range of oxides with perovskite or perovskite-related structure.