Giant circular dichroism in individual carbon nanotubes induced by extrinsic chirality

TL;DR

This paper demonstrates that extrinsic chirality can induce giant circular dichroism in individual carbon nanotubes, enabling polarization control at the nanoscale for advanced photonic applications.

Contribution

It reveals a new method to achieve large circular dichroism in single nanotubes through extrinsic chirality, with potential for nanoscale polarization manipulation.

Findings

Achieved 65% polarization degree in individual nanotubes.

Dependent on incidence angle, confirming mirror symmetry breaking.

Proposed charge distribution mechanism for giant dichroism.

Abstract

Circular dichroism is widely used for characterizing organic and biological materials, but measurements at a single molecule level are challenging because differences in absorption for opposite helicities are small. Here we show that extrinsic chirality can induce giant circular dichroism in individual carbon nanotubes, with degree of polarization reaching 65%. The signal has a large dependence on the incidence angle, consistent with the interpretation that mirror symmetry breaking by the optical wave vector is responsible for the effect. We propose that field-induced charge distribution results in an efficient polarization conversion, giving rise to the giant dichroism. Our results highlight the possibility of polarization manipulation at the nanoscale for applications in integrated photonics and novel metamaterial designs.