Spin lock composite and shaped pulses for efficient and robust pumping of dark states in magnetic resonance

TL;DR

This paper introduces composite and shaped pulses that improve the efficiency and robustness of pumping long-lived dark states in magnetic resonance, overcoming energy dissipation and inhomogeneity issues.

Contribution

It extends previous work by designing novel composite and adiabatic pulses that outperform traditional methods in creating dark states in chemically equivalent spins.

Findings

Effective in chemically equivalent spin pairs

Reduces energy dissipation during excitation

Applicable to various spectroscopic regimes

Abstract

Long-lived (symmetry protected) hyperpolarized spin states offer important new opportunities (for example, in clinical MR imaging), but existing methods for producing these states are limited by either excess energy dissipation or high sensitivity to inhomogeneities. We extend recent work on continuous-wave irradiation of nearly-equivalent spins (spin-lock induced crossing) by designing composite pulse and adiabatic shaped-pulse excitations which overcome the limitations. These composite and adiabatic pulses differ drastically from the traditional solutions in two-level systems. We also show this works in chemically equivalent spin pairs, which has the advantage of allowing for polarization transfer from and to remote spins. The approach is broadly applicable to systems where varying excitation strength induces an avoided crossing to a dark state, and thus to many other spectroscopic regimes.