ReBe2B5O11 (Re = Y, Gd)- A Series of Rare Earth Beryllium Borates as Deep-Ultraviolet Nonlinear Optical Materials

TL;DR

This paper reports the synthesis and structural analysis of new rare earth beryllium borates, ReBe2B5O11, with promising deep-ultraviolet nonlinear optical properties suitable for laser applications.

Contribution

It introduces a novel class of rare earth beryllium borates with unique layered structures and demonstrates their potential as deep-UV nonlinear optical materials.

Findings

Beta-ReBe2B5O11 has large nonlinear optical coefficients.

The materials have a short UV cut-off wavelength below 200nm.

The structures feature a novel platelike infinite superlayer [Be2B5O11]3-.

Abstract

The rapid developments of the deep-ultraviolet (deep-UV) laser science and technology urgently demand the nonlinear optical crystals which have large band gap enough to transmit the deep-UV light. Herein, we synthesized a series of new rare earth beryllium borates: ReBe2B5O11 (Re = Y, Gd). The structures of all these materials, for both alpha and beta phases, are featured by a novel platelike infinite superlayer [Be2B5O11]3-. Each [Be2B5O11]3- layer is further connected to the neighbor superlayer through Re3+ cations coordinating with O atoms. The beta-ReBe2B5O11 (Re=Y, Gd) have relatively large nonlinear optical coefficients and short UV cut-off wavelength below 200nm. Our investigations indicate that they are promising deep-UV NLO crystals.