Crack Formation in the Presence of an Electric Field in Droplets of Laponite Gel

TL;DR

This study investigates how applying a radial electric field influences crack patterns in drying droplets of Laponite gel, revealing reproducible patterns and empirical relations for crack formation timing and quantity.

Contribution

It demonstrates the effect of electric fields on crack pattern formation in colloidal gel droplets and introduces empirical scaling relations for predicting crack behavior.

Findings

Cracks form at a constant energy dissipation under DC voltage.

Switching off the field before cracking allows prediction of crack timing and number.

Electric field parameters significantly influence crack pattern characteristics.

Abstract

When a colloidal gel dries through evaporation, cracks are usually formed, which often reveal underlying processes at work during desiccation. Desiccating colloid droplets of few hundred $\mu l$ size show interesting effects of pattern formation and cracking which makes this an active subject of current research. Since aqueous gels of clay are known to be strongly affected by an electric field, one may expect crack patterns to exhibit a field effect. In the present study we allow droplets of laponite gel to dry under a radial electric field. This gives rise to highly reproducible patterns of cracks, which depend on the strength, direction and time of exposure to the electric field. For a continuously applied DC voltage, cracks always appear on dissipation of a certain constant amount of energy. If the field is switched off before cracks appear, the observed results are shown to obey a number of empirical scaling relations, which enable us to predict the time of appearance and the number of cracks under specified conditions.