Exact closed equation for reduced equilibrium distribution functions of the many-particle system
Victor F. Los

TL;DR
This paper derives an exact closed integrodifferential equation for the s-particle equilibrium distribution function in a many-particle system, using a projection operator approach and an expansion in particle density.
Contribution
It introduces a novel exact equation for reduced distribution functions and provides a linear approximation solution, advancing the theoretical understanding of many-particle equilibrium states.
Findings
Derived an exact integrodifferential equation for s-particle distributions.
Proposed a density expansion method for the equation kernel.
Obtained a linear approximation solution for the distribution functions.
Abstract
An exact closed equation for s - particle equilibrium distribution function (s<N) of the system of N>>1 interacting particles is obtained. This integra-differential {\beta} - convolution equation ({\beta}=1/k_{B}T) follows from the Bloch equation for the canonical distribution function by applying the projection operator integrating off the coordinates of N-s irrelevant particles. The method of expansion of the obtained equation kernel in the particle density n is suggested. The solution to this equation in the linear in n approximation for the kernel is found.
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Taxonomy
TopicsTheoretical and Computational Physics · Advanced Thermodynamics and Statistical Mechanics · Statistical Mechanics and Entropy
