Time Response Dynamics of Plasmon Excitation in Cobalt Nanoparticles on Glass Substrate

TL;DR

This study investigates the ultrafast electronic relaxation dynamics of plasmon excitation in cobalt nanoparticles on glass, revealing rapid excitation and relaxation times using femtosecond pump-probe spectroscopy.

Contribution

It provides the first measurement of femtosecond-scale plasmon relaxation times in cobalt nanoparticles on glass substrates using ultrafast spectroscopy.

Findings

Plasmon excitation is inhomogeneously broadened.

Excitation time is approximately 23 femtoseconds.

Relaxation time is approximately 97 femtoseconds.

Abstract

We use ultrafast pump-probe transmission spectroscopy to measure the electronic relaxation time for electrons in cobalt nanoparticles embedded on glass substrate using femtosecond laser pulses. We found that the plasmon excitation is inhomogenously broadening with a fast excitation time of 23 fs. and a plasmonic relaxation time of 97fs. The femtosecond laser pulses used in this experiment were come from a Ti:Sapphire resonator that uses a self-mode-locking mechanism based on the nonlinear Kerr effect. The pulses were found to have repetition rate of 103.52MHz with a pulse width of 64.5 fs at FWHM, and 810nm center wavelength.