On the gauge of the natural lineshape

TL;DR

This paper investigates how the choice of gauge affects the natural lineshape in spontaneous emission within nonrelativistic quantum electrodynamics, proposing methods to compare theoretical predictions with experimental results.

Contribution

It introduces a gauge-dependent formulation of the lineshape calculation and explores different excitation processes, including resonant absorption and laser pulse excitation.

Findings

Lineshape depends on gauge choice

Resonance fluorescence rate derived for hydrogen

Potential experimental test to determine best gauge description

Abstract

We use a general formulation of nonrelativistic quantum electrodynamics in which the gauge freedom is carried by the arbitrary transverse component of the the Green's function for the divergence operator to calculate the natural lineshape of spontaneous emission, thus discerning the full dependence of the result on the choice of gauge. We also use a representation of the Hamiltonian in which the virtual field associated with the atomic ground state is explicitly absent. We consider two processes by which the atom is excited; the first is resonant absorption of incident radiation with a sharp line. This treatment is then adapted to derive a resonance fluorescence rate associated with the Lamb line in atomic hydrogen. Second we consider the atom's excitation due to irradiation with a laser pulse treated semi-classically. An experiment could be used to reveal which of the calculated lineshape distributions is closest to the measured one. This would provide an answer to a question of fundamental importance; how does one best describe atom-radiation interactions with the canonical formalism?