Sub-Doppler optical resolution by confining a vapour in a nanostructure

TL;DR

This paper demonstrates sub-Doppler optical resolution by confining a thermal vapor within a nanostructure, revealing narrow spectral features due to 3-D vapor confinement, with potential applications in optical clocks and high-resolution spectroscopy.

Contribution

It introduces a novel method of achieving sub-Doppler spectral features in thermal vapor using nanostructure confinement, a phenomenon previously unseen at optical frequencies.

Findings

Observation of sub-Doppler structures in reflection spectra

Narrow spectral features originate from interstitial regions of the opal

Potential for micron-scale optical frequency references

Abstract

We show that a thermal vapor confined in a nanostructure is of spectroscopic interest. We perform reflection spectroscopy on a Cs vapour cell whose window is covered with a thin opal film (typically, 10 or 20 layers of ~ 1{\mu}m diameter spheres). Sub-Doppler structures appear in the optical spectrum in a purely linear regime of optical excitation and the signal is shown to originate from the interstitial regions of the opal. These narrow spectral structures, observable for a large range of oblique incidence angles (~ 30-50°), are an original feature associated to the 3-D vapor confinement. It remembers a Dicke narrowing, i.e. a Doppler broadening suppression when the atomic motion is sub-wavelength confined. This narrowing, commonly observed in the r.f. domain when a buffer gas ensures a collision confinement effect, had remained elusive in the optical frequency. Also, we describe preliminary experiments performed in a pump-probe technique, intended to elucidate the spatial origin of the narrow contribution. We finally discuss how our results allow envisioning micron-size references for optical frequency clocks, and high resolution spectroscopy of weak and hard-to-saturate molecular lines.