Metallic bonds become molecular-like in atomic-sized devices

TL;DR

This study reveals that metallic bonds in atomic-sized devices exhibit directional, molecule-like characteristics, providing high stability and opening new avenues for molecular electronics without interface issues.

Contribution

It demonstrates that metallic bonds at atomic scales become directional and stronger, resembling covalent bonds, which enhances stability and potential for molecular electronic applications.

Findings

Atomic-sized metallic bonds are directional and stronger than bulk

Measured forces align with vector sums of atomic interactions

Results suggest metallic bonds can behave like covalent bonds at small scales

Abstract

Covalent molecules are characterized by directed bonds, which provide stability-of-form to the molecules relative atomic positions. In contrast, bulk metals are characterized by delocalized bonds, where a large number of resonance structures ensure their high stability. However, reduced to atomic dimensions, metallic arrangements become increasingly vulnerable to disruptive entropic fluctuations. Using the smallest possible device, namely, a single atom held between two atomically sharp probes, force to rupture single-atom bridges was measured with pico-level resolution, using gold and silver. Remarkably, measured forces are found to be a precise vector sum (directional bonding) of cohesive forces between the central and adjacently coordinated atoms. Over three to four times stronger than bulk, the directional bonds provide high configurational stability to atomic-sized metallic devices, just as delocalization-induced resonance stabilization is the emergent response of bulk metals. Results open new opportunity for molecular electronics without complications arising from metal/molecule interfaces.