Persistent non-metallic behavior in Sr2IrO4 and Sr3Ir2O7 at high pressures

TL;DR

This study investigates the electronic behavior of Sr2IrO4 and Sr3Ir2O7 under high pressure, revealing persistent insulating states in Sr2IrO4 and proximity to a metal-insulator transition in Sr3Ir2O7, with no pressure-induced metallicity observed.

Contribution

First high-pressure resistivity measurements on Sr2IrO4 and Sr3Ir2O7, showing their contrasting responses and proximity to metal-insulator transition in Sr3Ir2O7.

Findings

No metallic transition in Sr2IrO4 up to 55 GPa.

Significant gap reduction in Sr3Ir2O7 up to 104 GPa.

Sr3Ir2O7 remains near a metal-insulator transition.

Abstract

Iridium-based 5d transition-metal oxides are attractive candidates for the study of correlated electronic states due to the interplay of enhanced crystal-field, Coulomb and spin-orbit interaction energies. At ambient pressure, these conditions promote a novel Jeff = 1/2 Mott insulating state, characterized by a gap of the order of ~0.1 eV. We present high-pressure electrical resistivity measurements of single crystals of Sr2IrO4 and Sr3Ir2O7. While no indications of a pressure-induced metallic state up to 55 GPa were found in Sr2IrO4, a strong decrease of the gap energy and of the resistance of Sr3Ir2O7 between ambient pressure and 104 GPa confirm that this compound is in the proximity of a metal-insulator transition.