Magnetocaloric effect and its implementation in critical behavior study of Mn4FeGe3-xSix intermetallic compounds

TL;DR

This study investigates the magnetocaloric effect in Mn4FeGe3-xSix compounds, revealing their potential for room-temperature magnetic refrigeration and analyzing their critical magnetic behavior.

Contribution

It provides the first detailed analysis of the magnetocaloric properties and critical behavior of Mn4FeGe3-xSix compounds, including the effect of Si substitution.

Findings

Large magnetic entropy change near room temperature

Second-order magnetic phase transition observed

Different magnetic interaction regimes identified for various compositions

Abstract

Magnetocaloric effect in Mn4FeGe3-xSix compounds has been studied by dc magnetization measurements. For the parent compound Mn4FeGe3, the paramagnetic to ferromagnetic transition temperature TC is above room temperature (320 K), which initially remains constant for small Si substitution at the Ge site and then decreases marginally with an increase in Si concentration. A large change in magnetic entropy at the TC, under a magnetic field variation of 50 kOe, with typical values of 5.9, 6.5, 5.9 and 4.4 J kg-1 K-1 for x = 0, 0.2, 0.6, and 1 samples, respectively, along with a broad operating temperature range and a negligible hysteresis make Mn4FeGe3-xSix series a promising candidate for magnetic refrigerant material around room temperature. Mn4FeGe3-xSix series is found to undergo a second-order magnetic phase transition. The field dependence of the magnetic entropy change has been brought out and implemented it to deduce the critical exponents. The critical behavior study shows that the magnetic interactions for x = 0 and 0.2 samples have two different behaviors below and above TC. Below TC, it follows the mean field theory with long-range magnetic interaction and above TC it follows the Heisenberg three-dimensional model with short-range or local magnetic interaction. The magnetic exchange interactions for the x = 0.6 and 1 samples follow the mean-field theory.