Excitation and deexcitation processes in atom-Rydberg atom collisions in helium-rich white dwarf atmospheres
V.A. Sreckovic, A.A. Mihajlov, Lj.M. Ignjatovic, and M.S. Dimitrijevic

TL;DR
This paper investigates non-elastic excitation and deexcitation collisions between helium Rydberg atoms and ground state helium in helium-rich white dwarf atmospheres, highlighting their significant role in atomic population dynamics.
Contribution
It demonstrates that atom-Rydberg atom processes are crucial and often dominant in influencing helium atom populations in certain white dwarf atmospheric conditions.
Findings
Atom-Rydberg processes significantly affect helium excitation in white dwarf atmospheres.
These processes are comparable or dominant over electron-atom processes in weakly ionized layers.
Implications for modeling white dwarf atmospheres and spectral analysis.
Abstract
We aim to show the importance of non-elastic excitation and deexcitation processes in collisions with the principal quantum number for helium-rich white dwarf atmospheres. We compare the efficiencies of these processes with those of the known non-elastic electron- atom processes in the atmospheres of some DB white dwarfs. We show that in significant parts of the considered atmospheres, which contain weakly ionized layers (the ionization degree ), the influence of the studied atom-Rydberg atom processes on excited helium atom populations is dominant or at least comparable to the influence of the concurrent electron--atom processes.
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