On the evolution of the non exchange spring behaviour to the exchange spring behaviour: A First Order Reversal Curve Analysis

TL;DR

This study investigates the transition from non-exchange to exchange spring magnet behaviour in Cobalt Ferrite-Strontium Ferrite nanocomposites by analyzing magnetization reversal using FORC and Henkel plots, highlighting the influence of particle size.

Contribution

It demonstrates how particle size controls the magnetization reversal mechanism and exchange interactions in nanocomposites, using FORC analysis to distinguish between different magnetic behaviours.

Findings

Lower particle size shows single coherent switching behavior.

Higher particle size exhibits separate switching peaks for soft and hard phases.

Exchange interactions dominate in composites with smaller particles.

Abstract

The magnetization behaviour of the soft Cobalt Ferrite-hard Strontium Ferrite nanocomposite is tuned from the non exchange spring nature to the exchange spring nature, by controlling the particle size of the soft Cobalt Ferrite in the Cobalt Ferrite: Strontium Ferrite (1:8) nanocomposite. The relative strength of the interaction governing the magnetization process in the nanocomposites is investigated using Henkel plot and First Order Reversal Curve (FORC) method. The FORC method has been utilized to understand the magnetization reversal behaviour as well as the extent of the irreversible magnetization present in both the nanocomposites having smaller and larger particle size of the Cobalt Ferrite. The magnetization process is primarily controlled by the domain wall movement in the nanocomposites. Using the FORC distribution in the (Ha, Hb) co-ordinate, the onset of the nucleation field, invasion of the domain wall from the soft to the hard phase, domain wall annihilation and the presence of the reversible magnetization with the applied reversal field for both the nanocomposites has been investigated. It has been found that for the composite having lower particle size of the soft phase shows a single switching behaviour corresponding to the coherent reversal of the both soft and hard phases. However, the composite having higher Cobalt Ferrite particle size shows two peak behaviour in the FORC distribution resembling individual switching of the soft and hard phases. The FORC distribution in (Hu, Hc) co-ordinate and the Henkel measurement confirms the dominant exchange interaction in the nanocomposites exhibiting exchange spring behaviour where as the occurrence of both the dipolar and exchange interaction is substantiated for the non exchange coupled nanocomposite.