Effect of Mg diffusion on bilayer photoluminescence spectra of Mg0.29Zn0.71O/ZnO interface at different annealing temperatures

TL;DR

This study investigates how Mg diffusion affects the photoluminescence spectra of MgZnO/ZnO bilayers, showing that annealing temperature influences interface diffusion and spectral properties, with a developed model linking diffusion profiles to PL spectra.

Contribution

It introduces a theoretical model that correlates Mg diffusion profiles with PL spectra changes in MgZnO/ZnO bilayers after annealing.

Findings

Mg diffusion confirmed by SIMS and absorption measurements.

Annealing at 900°C results in a single PL peak indicating complete intermixing.

Intermediate annealing causes spectral shifts indicating partial diffusion.

Abstract

Mg0.29Zn0.71O/ZnO (MZO/ZnO) bilayers were grown on sapphire substrates by pulsed laser deposition at ~ 400 C and were subsequently annealed at different temperatures ranging from ~ 500 to 900 C to allow diffusion of Mg across the interface. The diffusion of Mg was confirmed from secondary ion mass spectroscopy (SIMS) and Photo-absorption measurements on the samples. As a result of Mg diffusion the photoluminescence (PL) spectra of the bilayers got significantly modified. Whereas the as grown structure had two distinct near band edge UV luminescence peaks corresponding to the ZnO and MZO layer, the one annealed at ~ 900 C had a single near band edge PL peak corresponding to a complete intermixed layer. At the intermediate annealing temperature of ~800 C the PL peak position corresponding to the MZO layer red-shifted while that corresponding to the ZnO layer blue-shifted, implying a diffused interface and partial intermixing. A theoretical model has been developed and numerically simulated to correlate the PL spectra of the bilayers with the Mg diffusion profile across the interface, as measured by SIMS.