Structure and magnetic interactions in the solid solution Ba3-xSrxCr2O8

TL;DR

This study synthesizes and characterizes the solid solution Ba3-xSrxCr2O8, revealing how magnetic interactions within Cr5+ dimers vary with composition, using advanced crystal growth and magnetic measurements.

Contribution

First synthesis of polycrystalline and single crystalline Ba3-xSrxCr2O8 with detailed structural and magnetic analysis across compositions.

Findings

Cell parameters depend on composition.

Magnetic interaction Jd varies non-monotonically with x.

Single crystals successfully grown using floating zone technique.

Abstract

Solid solutions of the magnetic insulators Ba3Cr2O8 and Sr3Cr2O8 (Ba3-xSrxCr2O8) have been prepared in polycrystalline form for the first time. Single crys- talline material was obtained using a mirror image floating zone technique. X-ray diffraction data taken at room temperature indicate that the space group of Ba3-xSrxCr2O8 remains unchanged for all values of x, while the cell parameters depend on the chemical composition, as expected. Magnetization data, measured from 300 K down to 2 K, suggests that the interaction constant Jd within the Cr5+ dimers varies in a peculiar way as a function of x, starting at Jd = 25K for x = 0, then first slightly dropping to Jd = 18K for x = 0.75, before reaching Jd = 62K for x = 3.